I had one when I went travelling last year. They work in certain hole in the wall machines but not all. I think there is a guide somewhere which tells you where you can withdraw cash in each country. Mine couldn't be used for petrol. Maybe there are different types. To my knowledge they are not like debit or credit cards where you can pay for things. I could only take money out of a machine.
Try Visca cards. I got mine through my cantonal bank. The only problem I have is that it takes about 7 business to show your deposit. But since I know when my travel days are, that usually isn't a problem.